Consider:
struct mystruct_A
{
char a;
int b;
char c;
} x;
struct mystruct_B
{
int b;
char a;
} y;
The sizes of the structures are 12 and 8 respectively.
Are these structures padded or packed?
When does padding or packing take place?
Structure packing is only done when you tell your compiler explicitly to pack the structure. Padding is what you're seeing. Your 32-bit system is padding each field to word alignment. If you had told your compiler to pack the structures, they'd be 6 and 5 bytes, respectively. Don't do that though. It's not portable and makes compilers generate much slower (and sometimes even buggy) code.