Consider this example from w3schools:
<?xml version="1.0" encoding="ISO-8859-1"?>
<bookstore>
<book category="COOKING">
<title lang="en">Everyday Italian</title>
<author>Giada De Laurentiis</author>
<year>2005</year>
<price>30.00</price>
</book>
<book category="CHILDREN">
<title lang="en">Harry Potter</title>
<author>J K. Rowling</author>
<year>2005</year>
<price>29.99</price>
</book>
<book category="WEB">
<title lang="en">XQuery Kick Start</title>
<author>James McGovern</author>
<author>Per Bothner</author>
<author>Kurt Cagle</author>
<author>James Linn</author>
<author>Vaidyanathan Nagarajan</author>
<year>2003</year>
<price>49.99</price>
</book>
<book category="WEB">
<title lang="en">Learning XML</title>
<author>Erik T. Ray</author>
<year>2003</year>
<price>39.95</price>
</book>
</bookstore>
xmlstarlet sel -t -v "//@category" books.xml
returns only COOKING. How to get all attributes named category?
BONUS question: how do I evaluate XPath queries against an XML file without opening it in an editor nor program (I want a quick tool). The issue is that loading the huge file into memory crashes the editor. Don't tell me that eXist is my best bet?
Is this what you need?
or to separate the results on each line
Update
You're right, your XPath was good, you just need different parameters.
Regarding why the original doesn't work: XSLT 1.0 value-of is defined to work like XPath's string() function, and string(node-set) => string(first-node). See also Feature Request: value-of multiple nodes should concat values of all nodes